##TITLE=	29Si MAS NMR spectrum of synthetic zeolite heulandite
##JCAMP-DX=	5.01
##DATA TYPE=	NMR SPECTRUM
##DATA CLASS=	XYDATA
##ORIGIN=	"Khodabandeh and Davis, Chem. Commun., 1205-1206 (1996) Figure 3"
##OWNER=	"processed by H. Koller, University of Münster"
##LONG DATE=	20.12.2019 14:00
##SOURCE REFERENCE=	HEU-29Si-Khodabandeh-1996_HEU
##DATA PROCESSING=	"Spectrum digitized with WebPlotDigitizer and deconvoluted with dmfit: D. Massiot et al., Magn. Reson. Chem., 40, 70-76 (2002)"
	
$$Sample information	
##NAMES=	HEU
##NAMES=	hydrated heulandite
##NAMES=	hydrated heulandite
##SAMPLE DESCRIPTION=	"synthetic heulandite"
##TEMPERATURE=	N.A.
	
"
$$Bibliographic information"	
##$AUTHORS=	"Khodabandeh, S., Davis, M.E."
##$TITLE=	"Synthesis of a heulandite-type zeolite by hydrothermal conversion of zeolite Pl"
##$JOURNAL=	Chem. Commun.
##$VOLUME=	
##$PAGES=	1205-1206
##$YEAR=	1996
##$DOI=	10.1039/cc9960001205
##$FIGURE=	Figure 3
	
$$Peak information	(Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=	4
##$PEAK TSITES=	0                    0                    0                    0                                                                                                                                                                                                                                                                                                                                                                                                                                                         
##$PEAK LABELS=	A                   B                    C                    D                                                                                                                                                                                                                                                                                                                                                                                                                                                         
##$Q TYPE=	Q4(0Al)      Q4(1Al)      Q4(2Al)      Q4(3Al)                                                                                                                                                   
##$PEAK POSITIONS=	-111.41        -104.63        -98.44        -93.44                                                                                                                                                                 
##$PEAK AREAS=	8.37             56.11             31.26             4.25                                                                                                                                                                                                    
##$PEAK WIDTHS=	3.41               6.1               4.39               2.73                                                                                                                                                                                                                  
##$PEAK SHAPES=	0.5               0.5               0.5               0.5                                                                                                                                                                                                                  
##$PEAK_CQ=	
##$PEAK_etaQ=	
##$NUMBERING REF=	
##$ASSIGN REF=	
##$ASSIGN METHOD=	
	
$$Spectrum acquisition information	
##.OBSERVE NUCLEUS=	29Si
##.OBSERVE FREQUENCY=	59.66
##.PULSE SEQUENCE=	single pulse
##.MAS FREQUENCY=	
	
$$Spectrum data information	
##XUNITS=	ppm
##YUNITS=	arbitrary units
##FIRSTX=	-50.40
##LASTX=	-148.80
##XFACTOR=	1
##YFACTOR=	1
##NPOINTS=	985
##FIRSTY=	0.0180
	
$$Spectrum data	
##XYDATA=	(X++(Y..Y))
-50.4000	0.0181
-50.5000	0.0181
-50.6000	0.0182
-50.7000	0.0182
-50.8000	0.0183
-50.9000	0.0184
-51.0000	0.0185
-51.1000	0.0185
-51.2000	0.0186
-51.3000	0.0187
-51.4000	0.0187
-51.5000	0.0188
-51.6000	0.0189
-51.7000	0.0190
-51.8000	0.0190
-51.9000	0.0191
-52.0000	0.0192
-52.1000	0.0159
-52.2000	0.0148
-52.3000	0.0149
-52.4000	0.0161
-52.5000	0.0151
-52.6000	0.0118
-52.7000	0.0107
-52.8000	0.0108
-52.9000	0.0109
-53.0000	0.0087
-53.1000	0.0088
-53.2000	0.0100
-53.3000	0.0112
-53.4000	0.0124
-53.5000	0.0114
-53.6000	0.0114
-53.7000	0.0115
-53.8000	0.0116
-53.9000	0.0117
-54.0000	0.0117
-54.1000	0.0118
-54.2000	0.0142
-54.3000	0.0165
-54.4000	0.0166
-54.5000	0.0166
-54.6000	0.0201
-54.7000	0.0213
-54.8000	0.0214
-54.9000	0.0237
-55.0000	0.0260
-55.1000	0.0250
-55.2000	0.0273
-55.3000	0.0296
-55.4000	0.0297
-55.5000	0.0298
-55.6000	0.0321
-55.7000	0.0333
-55.8000	0.0345
-55.9000	0.0346
-56.0000	0.0347
-56.1000	0.0348
-56.2000	0.0349
-56.3000	0.0349
-56.4000	0.0339
-56.5000	0.0329
-56.6000	0.0318
-56.7000	0.0297
-56.8000	0.0275
-56.9000	0.0242
-57.0000	0.0220
-57.1000	0.0199
-57.2000	0.0166
-57.3000	0.0122
-57.4000	0.0100
-57.5000	0.0079
-57.6000	0.0057
-57.7000	0.0024
-57.8000	-0.0020
-57.9000	-0.0042
-58.0000	-0.0063
-58.1000	-0.0074
-58.2000	-0.0084
-58.3000	-0.0095
-58.4000	-0.0116
-58.5000	-0.0149
-58.6000	-0.0171
-58.7000	-0.0181
-58.8000	-0.0169
-58.9000	-0.0179
-59.0000	-0.0201
-59.1000	-0.0234
-59.2000	-0.0233
-59.3000	-0.0232
-59.4000	-0.0231
-59.5000	-0.0231
-59.6000	-0.0230
-59.7000	-0.0229
-59.8000	-0.0228
-59.9000	-0.0227
-60.0000	-0.0215
-60.1000	-0.0192
-60.2000	-0.0180
-60.3000	-0.0179
-60.4000	-0.0178
-60.5000	-0.0178
-60.6000	-0.0177
-60.7000	-0.0165
-60.8000	-0.0153
-60.9000	-0.0152
-61.0000	-0.0162
-61.1000	-0.0162
-61.2000	-0.0127
-61.3000	-0.0104
-61.4000	-0.0114
-61.5000	-0.0113
-61.6000	-0.0113
-61.7000	-0.0112
-61.8000	-0.0111
-61.9000	-0.0110
-62.0000	-0.0109
-62.1000	-0.0131
-62.2000	-0.0130
-62.3000	-0.0130
-62.4000	-0.0140
-62.5000	-0.0150
-62.6000	-0.0138
-62.7000	-0.0138
-62.8000	-0.0137
-62.9000	-0.0136
-63.0000	-0.0135
-63.1000	-0.0135
-63.2000	-0.0134
-63.3000	-0.0133
-63.4000	-0.0132
-63.5000	-0.0143
-63.6000	-0.0153
-63.7000	-0.0153
-63.8000	-0.0152
-63.9000	-0.0151
-64.0000	-0.0150
-64.1000	-0.0150
-64.2000	-0.0149
-64.3000	-0.0159
-64.4000	-0.0170
-64.5000	-0.0169
-64.6000	-0.0168
-64.7000	-0.0168
-64.8000	-0.0167
-64.9000	-0.0166
-65.0000	-0.0177
-65.1000	-0.0187
-65.2000	-0.0187
-65.3000	-0.0186
-65.4000	-0.0185
-65.5000	-0.0196
-65.6000	-0.0206
-65.7000	-0.0206
-65.8000	-0.0205
-65.9000	-0.0204
-66.0000	-0.0204
-66.1000	-0.0203
-66.2000	-0.0191
-66.3000	-0.0179
-66.4000	-0.0179
-66.5000	-0.0178
-66.6000	-0.0177
-66.7000	-0.0177
-66.8000	-0.0176
-66.9000	-0.0175
-67.0000	-0.0175
-67.1000	-0.0174
-67.2000	-0.0162
-67.3000	-0.0151
-67.4000	-0.0150
-67.5000	-0.0149
-67.6000	-0.0149
-67.7000	-0.0148
-67.8000	-0.0148
-67.9000	-0.0147
-68.0000	-0.0146
-68.1000	-0.0146
-68.2000	-0.0145
-68.3000	-0.0133
-68.4000	-0.0122
-68.5000	-0.0132
-68.6000	-0.0143
-68.7000	-0.0142
-68.8000	-0.0153
-68.9000	-0.0164
-69.0000	-0.0163
-69.1000	-0.0163
-69.2000	-0.0151
-69.3000	-0.0139
-69.4000	-0.0139
-69.5000	-0.0138
-69.6000	-0.0138
-69.7000	-0.0126
-69.8000	-0.0114
-69.9000	-0.0114
-70.0000	-0.0113
-70.1000	-0.0113
-70.2000	-0.0124
-70.3000	-0.0101
-70.4000	-0.0089
-70.5000	-0.0111
-70.6000	-0.0111
-70.7000	-0.0099
-70.8000	-0.0099
-70.9000	-0.0087
-71.0000	-0.0064
-71.1000	-0.0041
-71.2000	-0.0052
-71.3000	-0.0040
-71.4000	-0.0029
-71.5000	-0.0006
-71.6000	-0.0006
-71.7000	-0.0005
-71.8000	-0.0005
-71.9000	-0.0005
-72.0000	-0.0004
-72.1000	-0.0004
-72.2000	-0.0003
-72.3000	-0.0003
-72.4000	-0.0003
-72.5000	-0.0003
-72.6000	-0.0002
-72.7000	-0.0002
-72.8000	-0.0002
-72.9000	-0.0001
-73.0000	-0.0001
-73.1000	-0.0001
-73.2000	-0.0001
-73.3000	0.0000
-73.4000	0.0000
-73.5000	0.0000
-73.6000	-0.0011
-73.7000	-0.0022
-73.8000	-0.0022
-73.9000	-0.0021
-74.0000	-0.0032
-74.1000	-0.0043
-74.2000	-0.0043
-74.3000	-0.0032
-74.4000	-0.0043
-74.5000	-0.0054
-74.6000	-0.0065
-74.7000	-0.0065
-74.8000	-0.0065
-74.9000	-0.0065
-75.0000	-0.0065
-75.1000	-0.0064
-75.2000	-0.0064
-75.3000	-0.0053
-75.4000	-0.0042
-75.5000	-0.0042
-75.6000	-0.0042
-75.7000	-0.0041
-75.8000	-0.0041
-75.9000	-0.0041
-76.0000	-0.0041
-76.1000	-0.0041
-76.2000	-0.0041
-76.3000	-0.0030
-76.4000	-0.0019
-76.5000	-0.0019
-76.6000	-0.0019
-76.7000	-0.0019
-76.8000	-0.0019
-76.9000	-0.0019
-77.0000	-0.0019
-77.1000	-0.0019
-77.2000	-0.0019
-77.3000	-0.0019
-77.4000	-0.0019
-77.5000	-0.0019
-77.6000	-0.0008
-77.7000	0.0003
-77.8000	0.0003
-77.9000	0.0003
-78.0000	0.0002
-78.1000	0.0002
-78.2000	0.0002
-78.3000	0.0002
-78.4000	0.0002
-78.5000	0.0001
-78.6000	0.0001
-78.7000	0.0001
-78.8000	0.0001
-78.9000	0.0001
-79.0000	0.0000
-79.1000	0.0000
-79.2000	0.0000
-79.3000	0.0000
-79.4000	-0.0001
-79.5000	-0.0001
-79.6000	-0.0001
-79.7000	-0.0002
-79.8000	-0.0036
-79.9000	-0.0047
-80.0000	-0.0048
-80.1000	-0.0070
-80.2000	-0.0093
-80.3000	-0.0082
-80.4000	-0.0094
-80.5000	-0.0128
-80.6000	-0.0151
-80.7000	-0.0151
-80.8000	-0.0152
-80.9000	-0.0163
-81.0000	-0.0175
-81.1000	-0.0176
-81.2000	-0.0176
-81.3000	-0.0177
-81.4000	-0.0177
-81.5000	-0.0200
-81.6000	-0.0200
-81.7000	-0.0201
-81.8000	-0.0179
-81.9000	-0.0180
-82.0000	-0.0180
-82.1000	-0.0181
-82.2000	-0.0181
-82.3000	-0.0170
-82.4000	-0.0149
-82.5000	-0.0115
-82.6000	-0.0105
-82.7000	-0.0094
-82.8000	-0.0061
-82.9000	-0.0050
-83.0000	-0.0062
-83.1000	-0.0052
-83.2000	-0.0041
-83.3000	-0.0042
-83.4000	-0.0042
-83.5000	-0.0043
-83.6000	-0.0032
-83.7000	-0.0022
-83.8000	-0.0022
-83.9000	-0.0023
-84.0000	-0.0024
-84.1000	-0.0024
-84.2000	-0.0025
-84.3000	-0.0003
-84.4000	-0.0004
-84.5000	-0.0005
-84.6000	-0.0006
-84.7000	-0.0006
-84.8000	0.0004
-84.9000	0.0015
-85.0000	0.0014
-85.1000	0.0013
-85.2000	0.0012
-85.3000	0.0012
-85.4000	0.0011
-85.5000	0.0010
-85.6000	0.0009
-85.7000	0.0009
-85.8000	0.0008
-85.9000	0.0007
-86.0000	0.0006
-86.1000	0.0017
-86.2000	0.0027
-86.3000	0.0026
-86.4000	0.0025
-86.5000	0.0024
-86.6000	0.0024
-86.7000	0.0023
-86.8000	0.0022
-86.9000	0.0021
-87.0000	0.0020
-87.1000	0.0008
-87.2000	0.0019
-87.3000	0.0029
-87.4000	0.0028
-87.5000	0.0038
-87.6000	0.0060
-87.7000	0.0070
-87.8000	0.0069
-87.9000	0.0091
-88.0000	0.0112
-88.1000	0.0145
-88.2000	0.0167
-88.3000	0.0188
-88.4000	0.0199
-88.5000	0.0220
-88.6000	0.0253
-88.7000	0.0286
-88.8000	0.0307
-88.9000	0.0329
-89.0000	0.0362
-89.1000	0.0417
-89.2000	0.0450
-89.3000	0.0471
-89.4000	0.0493
-89.5000	0.0525
-89.6000	0.0547
-89.7000	0.0568
-89.8000	0.0590
-89.9000	0.0622
-90.0000	0.0644
-90.1000	0.0665
-90.2000	0.0687
-90.3000	0.0697
-90.4000	0.0707
-90.5000	0.0718
-90.6000	0.0728
-90.7000	0.0772
-90.8000	0.0816
-90.9000	0.0815
-91.0000	0.0825
-91.1000	0.0891
-91.2000	0.0947
-91.3000	0.0979
-91.4000	0.1023
-91.5000	0.1078
-91.6000	0.1145
-91.7000	0.1211
-91.8000	0.1289
-91.9000	0.1355
-92.0000	0.1410
-92.1000	0.1465
-92.2000	0.1599
-92.3000	0.1733
-92.4000	0.1788
-92.5000	0.1854
-92.6000	0.1977
-92.7000	0.2122
-92.8000	0.2222
-92.9000	0.2277
-93.0000	0.2321
-93.1000	0.2387
-93.2000	0.2431
-93.3000	0.2464
-93.4000	0.2508
-93.5000	0.2585
-93.6000	0.2663
-93.7000	0.2684
-93.8000	0.2695
-93.9000	0.2716
-94.0000	0.2737
-94.1000	0.2748
-94.2000	0.2758
-94.3000	0.2768
-94.4000	0.2767
-94.5000	0.2777
-94.6000	0.2799
-94.7000	0.2798
-94.8000	0.2808
-94.9000	0.2852
-95.0000	0.2918
-95.1000	0.2984
-95.2000	0.3017
-95.3000	0.3061
-95.4000	0.3139
-95.5000	0.3216
-95.6000	0.3283
-95.7000	0.3405
-95.8000	0.3539
-95.9000	0.3650
-96.0000	0.3784
-96.1000	0.3963
-96.2000	0.4231
-96.3000	0.4511
-96.4000	0.4735
-96.5000	0.4902
-96.6000	0.5137
-96.7000	0.5495
-96.8000	0.5842
-96.9000	0.6066
-97.0000	0.6290
-97.1000	0.6536
-97.2000	0.6782
-97.3000	0.6983
-97.4000	0.7173
-97.5000	0.7363
-97.6000	0.7542
-97.7000	0.7720
-97.8000	0.7888
-97.9000	0.8044
-98.0000	0.8133
-98.1000	0.8188
-98.2000	0.8288
-98.3000	0.8377
-98.4000	0.8421
-98.5000	0.8443
-98.6000	0.8453
-98.7000	0.8474
-98.8000	0.8496
-98.9000	0.8495
-99.0000	0.8472
-99.1000	0.8426
-99.2000	0.8380
-99.3000	0.8311
-99.4000	0.8232
-99.5000	0.8164
-99.6000	0.8106
-99.7000	0.8027
-99.8000	0.7936
-99.9000	0.7823
-100.0000	0.7665
-100.1000	0.7529
-100.2000	0.7438
-100.3000	0.7348
-100.4000	0.7246
-100.5000	0.7144
-100.6000	0.7064
-100.7000	0.7029
-100.8000	0.6984
-100.9000	0.6915
-101.0000	0.6870
-101.1000	0.6835
-101.2000	0.6778
-101.3000	0.6732
-101.4000	0.6709
-101.5000	0.6719
-101.6000	0.6741
-101.7000	0.6785
-101.8000	0.6852
-101.9000	0.6918
-102.0000	0.6985
-102.1000	0.7119
-102.2000	0.7298
-102.3000	0.7443
-102.4000	0.7554
-102.5000	0.7688
-102.6000	0.7856
-102.7000	0.8046
-102.8000	0.8247
-102.9000	0.8449
-103.0000	0.8583
-103.1000	0.8728
-103.2000	0.8918
-103.3000	0.9109
-103.4000	0.9276
-103.5000	0.9455
-103.6000	0.9601
-103.7000	0.9701
-103.8000	0.9768
-103.9000	0.9823
-104.0000	0.9901
-104.1000	0.9968
-104.2000	0.9989
-104.3000	1.0000
-104.4000	0.9988
-104.5000	0.9987
-104.6000	0.9953
-104.7000	0.9907
-104.8000	0.9851
-104.9000	0.9783
-105.0000	0.9681
-105.1000	0.9568
-105.2000	0.9433
-105.3000	0.9320
-105.4000	0.9229
-105.5000	0.9150
-105.6000	0.9082
-105.7000	0.8980
-105.8000	0.8789
-105.9000	0.8586
-106.0000	0.8440
-106.1000	0.8315
-106.2000	0.8169
-106.3000	0.8022
-106.4000	0.7842
-106.5000	0.7606
-106.6000	0.7369
-106.7000	0.7167
-106.8000	0.7031
-106.9000	0.6874
-107.0000	0.6615
-107.1000	0.6401
-107.2000	0.6266
-107.3000	0.6052
-107.4000	0.5849
-107.5000	0.5725
-107.6000	0.5523
-107.7000	0.5264
-107.8000	0.5106
-107.9000	0.4994
-108.0000	0.4814
-108.1000	0.4712
-108.2000	0.4656
-108.3000	0.4453
-108.4000	0.4228
-108.5000	0.4138
-108.6000	0.4082
-108.7000	0.3980
-108.8000	0.3856
-108.9000	0.3744
-109.0000	0.3676
-109.1000	0.3620
-109.2000	0.3541
-109.3000	0.3462
-109.4000	0.3417
-109.5000	0.3405
-109.6000	0.3394
-109.7000	0.3360
-109.8000	0.3348
-109.9000	0.3371
-110.0000	0.3393
-110.1000	0.3415
-110.2000	0.3426
-110.3000	0.3460
-110.4000	0.3505
-110.5000	0.3538
-110.6000	0.3561
-110.7000	0.3572
-110.8000	0.3594
-110.9000	0.3617
-111.0000	0.3617
-111.1000	0.3616
-111.2000	0.3605
-111.3000	0.3583
-111.4000	0.3538
-111.5000	0.3493
-111.6000	0.3470
-111.7000	0.3437
-111.8000	0.3369
-111.9000	0.3280
-112.0000	0.3179
-112.1000	0.3078
-112.2000	0.2976
-112.3000	0.2909
-112.4000	0.2819
-112.5000	0.2718
-112.6000	0.2651
-112.7000	0.2550
-112.8000	0.2382
-112.9000	0.2270
-113.0000	0.2236
-113.1000	0.2079
-113.2000	0.1877
-113.3000	0.1776
-113.4000	0.1743
-113.5000	0.1721
-113.6000	0.1654
-113.7000	0.1553
-113.8000	0.1452
-113.9000	0.1340
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##END=	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
	
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